Deconstructive Functionalizations of Unstrained Carbon–Nitrogen Cleavage Enabled by Difluorocarbene
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چکیده
منابع مشابه
Difluoromethylation and gem-difluorocyclopropenation with difluorocarbene generated by decarboxylation.
Difluoromethylation of the activated X-H bond (X = N, O and S) and aliphatic thiols, and gem-difluorocyclopropenation of alkynes with difluorocarbene generated in situ from difluoromethylene phosphobetaine (Ph3P(+)CF2CO2(-)) by decarboxylation occurred smoothly without the presence of any base or other additives.
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ژورنال
عنوان ژورنال: ACS Central Science
سال: 2020
ISSN: 2374-7943,2374-7951
DOI: 10.1021/acscentsci.0c00779